Bibb was born in Bismarck, North Dakota and raised in Nelson County, Virginia. Her father died when she was three years old. Later, she and her mother, along with her three older sisters, moved to Richmond, Virginia, where she attended an all-girls Catholic high school, Saint Gertrude High School.

In 1990, The Oprah Winfrey Show and the Elite Agency held a nationwide modeling search. Bibb’s mother took photos of her then 16-year-old daughter and sent them in. The celebrity judges, John Casablancas, Naomi Campbell, Linda Evangelista and Iman were impressed and they picked her as the winner.

After finishing her junior year, Bibb flew to New York City and signed a contract with Elite Agency. She modeled over that summer, and went on a trip to Japan. She returned home for her senior year and graduated in 1992. Then she decided to attend the University of Virginia. After a single semester, she dropped out and moved to New York City to pursue a full-time modeling career. Her modelling photographs have appeared in such magazines as Maxim and FHM. She also attended the William Esper acting studio for three years.

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